Reactions of disulfur dinitride with antimony pentachloride
نویسندگان
چکیده
منابع مشابه
Synthesis of Antimony Nanotubes via Facile Template-Free Solvothermal Reactions
Uniform antimony (Sb) nanotubes were successfully synthesized via a facile solvothermal method without the need for any surfactants or templates. The Sb nanotubes are confirmed to be pure rhombohedral phase and have better crystallinity. These nanotubes show middle-hollow and open-ended structures, as well as multi-walled structures with the wall thickness of about 10 nm. Also, they have an ave...
متن کامل(Disulfur dinitrido)triphenylantimony(V)
The title compound, [Sb(C(6)H(5))(3)(N(2)S(2))], contains a molecular entity that is very similar to that of the known polymorph of Sb(S(2)N(2))Ph(3) [Kunkel et al. (1997 ▶). Z. Naturforsch. Teil B, 52, 193-198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S-N=S=N, consisting of one long S-N bond, an inter-mediate length N=S bond and a short S=N bond.
متن کاملIn Situ EXAFS Characterisation of the Synthesis of Polynuclear Chloroniobates from Sm Atom Reactions with Niobium Pentachloride
A new method to prepare solid state chlorometallates by reductive dechlorination of solvated niobium pentachloride with vaporisation of nominally free atoms of samanum is described. Products were prepared in an original set-up by evaporation of samarium into a mixed toluene solution of NbCl,, at 180 K. The local order around the Nb atoms was probed by EXAFS spectroscopy at the Nb K edge, using ...
متن کاملREACTIONS OF DIHYDROPYRIDINES WITH BENZYNE
Reactions of 1 ,Zdihydropyridines (la-c) and 1,4-dihydropyridines (2a-c) in the presence of benzyne (3) under thermal conditions, and in the case of (2c) under photochemical conditions, have been investigated. Benzyne acts as an oxidizing agent to convert dihydropyridine (la) and (2a) to the corresponding pyridine (4) or adds as a dienophile to (lb-c).
متن کاملThe interaction of molybdenum pentachloride with O- and S-heterocycles.
The 1 : 2 molar reactions of MoCl5, in dichloromethane at room temperature, with tetrahydrofuran (thf), tetrahydropyran (thp), dioxane and tetrahydrothiophene (tht) afforded, respectively, [Mo(O)Cl3(thf)]2, 1, and MoCl4(L)2 (L = thp, 2; dioxane, 3; tht, 4), in 81-87% yields. The molecular structures of 1, 2 and 4 were ascertained by X-ray diffractometry. DFT and spectroscopic (IR, NMR) studies ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 1969
ISSN: 0020-1669,1520-510X
DOI: 10.1021/ic50077a003